Anorganische Molekülchemie


Synthesis, Electronic Properties and Reactivity of [B12X11(NO2)]2- (X = F I) Dianions
Knut R. Asmis, Björn B. Beele, Carsten Jenne, Sebastian Kawa, Harald Knorke, Marc C. Nierstenhöfer, Xue-Bin Wang, Jonas Warneke, Ziyan Warneke, Qinqin Yuan
Chem. Eur. J. 2020, 26, 14594-14601

Direct functionalization of C−H bonds by electrophilic anions
Jonas Warneke, Martin Mayer, Markus Rohdenburg, Xin Ma, Judy K. Y. Liu, Max Grellmann, Sreekanta Debnath, Vladimir A. Azov, Edoardo Apra, Robert P. Young, Carsten Jenne, Grant E. Johnson, Hilkka I. Kenttämaa, Knut R. Asmis, Julia Laskin
Proc. Natl. Acad. Sci. U.S.A. 2020, 117, 23374-23379

Properties of gaseous closo-[B6X6]2‒ dianions (X = Cl, Br, I)
Markus Rohdenburg, Zheng Yang, Pei Su, Eduard Bernhardt, Qinqin Yuan, Edoardo Apra, Simon Grabowsky, Julia Laskin, Carsten Jenne, Xue-Bin Wang, Jonas Warneke
Phys. Chem. Chem. Phys. 2020, 22, 17713-17724

Insights into the Structure of Halide-Rich Hydrochloric and Hydrobromic Acid – A Structural and Quantum-Chemical Investigation of the [H6X4O2]2- (X = Cl, Br) Anions
Philipp Bertocco, Christoph Bolli, Bruno A. Correia Bicho, Carsten Jenne, Marc C. Nierstenhöfer
J. Chem. Crystallogr. 2020, 50, 69-76

First steps towards a stable neon compound: Observation and bonding analysis of [B12(CN)11Ne]-
Martin Mayer, Markus Rohdenburg, Valentin van Lessen, Marc C. Nierstenhöfer, Edoardo Aprà, Simon Grabowsky, Knut R. Asmis, Carsten Jenne, Jonas Warneke
Chem. Commun. 2020, 56, 4591-4594

[Se(CH2C(O)CH3)3][B12F11NH3]: The first selenium cation with three β-ketone substituents
Carsten Jenne, Marc C. Nierstenhöfer
Acta Crystallogr., Sect. E: Struct. Rep. Online 2020, 76, 221-224

Homopolyatomic Chalcogen Radical Cations of Selenium and Tellurium
Carsten Jenne, Marc C. Nierstenhöfer
Eur. J. Inorg. Chem. 2020, 200-207


The Structure of Proton-bound Triethylammonia B12X122‒ (X = F, Cl) Clusters
Patrick J. J. Carr, Jonas Warneke, Josh Featherstone, Carsten Jenne, Estelle Loire, W. Scott Hopkins
Mol. Phys. 2019, 117, 2972-2979

Successive Photoswitching and Derivatization Effects in Photochromic DTE-based Coordination Cages
Ru-Jin Li, Muxin Han, Jacopo Tessarolo, Julian J. Holstein, Jens Lübben, Birger Dittrich, Christian Volkmann, Maik Finze, Carsten Jenne, Guido H. Clever
ChemPhotoChem 2019, 6, 378-383

Rational design of an argon-binding superelectrophilic anion
Martin Mayer, Valentin van Lessen, Markus Rohdenburg, Gao-Lei Hou, Zheng Yang, Rüdiger M. Exner, Edoardo Aprà, Vladimir A. Azov, Simon Grabowsky, Sotiris S. Xantheas, Knut R. Asmis, Xue-Bin Wang, Carsten Jenne, Jonas Warneke
Proc. Natl. Acad. Sci. U.S.A. 2019, 116, 8167-8172

Na+[Me3NB12Cl11]-•SO2: a rare example of a sodium–SO2 complex
Carsten Jenne, Valentin van Lessen
Acta Crystallogr., Sect. E: Struct. Rep. Online 2019, 75, 607-610

Temperature- and solvate-dependent disorder in the crystal structure of [PNP]+[HSO4]
Carsten Jenne, Marc C. Nierstenhöfer
Z. Naturforsch., B: Chem. Sci. 2019, 74, 373-379

Gas phase fragmentation of adducts between dioxygen and closo-borate radical anions
Jonas Warneke, Markus Rohdenburg, Judy K. Y. Liu, Erynn Johnson, Xin Ma, Rashmi Kumar, Pei Su, Edoardo Aprà, Xue-Bin Wang, Carsten Jenne, Maik Finze, Hilkka I. Kenttämaa, Julia Laskin
Int. J. Mass Spectrom. 2019, 436, 71-78


Silver salts of the weakly coordinating anion [Me3NB12Cl11]-
Carsten Jenne, Bianca Wegener
Z. Anorg. Allg. Chem.2018, 644, 1123-1132

Self-organizing layers from complex molecular anions
Jonas Warneke, Martin E. McBriarty, Shawn L. Riechers, Swarup China, Mark H. Engelhard, Edoardo Aprà, Robert P. Young, Nancy M. Washton, Carsten Jenne, Grant E. Johnson, Julia Laskin
Nat. Commun. 2018, 9, 1889


Electronic Structure and Stability of [B12X12]2- (X = F − At): A Combined Photoelectron Spectroscopic and Theoretical Study
Jonas Warneke, Gao-Lei Hou, Edoardo Aprà, Carsten Jenne, Zheng Yang, Zhengbo Qin, Karol Kowalski, Xue-Bin Wang, Sotiris S. Xantheas
J. Am. Chem. Soc. 2017, 139, 14749-14756

Halogenated closo-Dodecaborate Anions Stabilize Weakly Bound [(Me3NH)3X]2+ (X = Cl, Br) Dications in the Solid State
Christoph Bolli, Janis Derendorf, Carsten Jenne, Mathias Keßler
Eur. J. Inorg. Chem. 2017, 4552-4558

The First Step of the Oxidation of Elemental Sulfur: Crystal Structure of the Homopolyatomic Sulfur Radical Cation [S8]•+
Janis Derendorf, Carsten Jenne, Mathias Keßler
Angew. Chem. 2017, 129, 8395-8398; Angew. Chem. Int. Ed. 2017, 56, 8281-8284

Superelectrophilic Behavior of an Anion Demonstrated by Spontaneous Binding of [B12Cl11]- with Noble Gases
Markus Rohdenburg, Martin Mayer, Max Grellmann, Carsten Jenne, Tobias Borrmann, Florian Kleemiß, Vladimir A. Azov, Knut R. Asmis, Simon Grabowsky, Jonas Warneke
Angew. Chem. 2017, 129, 8090-8096; Angew. Chem. Int. Ed. 2017, 56, 7980-7985

Reaction of the Tricyanoborate Dianion [B(CN)3]2− with HgCl2
Eduard Bernhardt, Vera Bernhardt-Pitchougina, Carsten Jenne
Inorg. Chem. 2017, 56, 5465-5470

Improving the Solubility of Halogenated 1-Ammonio-closo-dodecaborate Anions
Philipp Bertocco, Janis Derendorf, Carsten Jenne, Christoph Kirsch
Inorg. Chem. 2017, 56, 3459-3466


The Me3NB12Cl11 radical – A strong one-electron oxidizing agent
Philipp Bertocco, Christoph Bolli, Janis Derendorf, Carsten Jenne, Axel Klein, Kathrin Stirnat
Chem. Eur. J. 2016, 22, 16032-16036

Evidence for an intrinsic binding force between dodecaborate dianions and receptors with hydrophobic binding pockets
Jonas Warneke, Carsten Jenne, Johannes Bernarding, Vladimir A. Azov, Markus Plaumann
Chem. Commun. 2016, 52, 6300-6303

A Theoretical and Synthetic Study on the Existence, Structures, and Bonding of the Halide-Bridged [B2X7]- (X = F, Cl, Br, I) Anions
Philipp Bertocco, Christoph Bolli, Bruno A. Correia Bicho, Carsten Jenne, Berrin Erken, Risto S. Laitinen, Helene A. Seeger, Teemu T. Takaluoma
Inorg. Chem. 2016, 55, 3599-3604

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